A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

Xu-Sheng Du; Qiong Jia; Chun-Yu Wang; Kamel Meguellati; Ying-Wei Yang

doi:10.1039/c9cc01947b

A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

Chem Commun (Camb). 2019 May 14;55(40):5736-5739. doi: 10.1039/c9cc01947b.

Authors

Xu-Sheng Du¹, Qiong Jia, Chun-Yu Wang, Kamel Meguellati, Ying-Wei Yang

Affiliation

¹ International Joint Research Laboratory of Nano-Micro Architecture Chemistry (NMAC), College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China. kamel_m@jlu.edu.cn ywyang@jlu.edu.cn.

PMID: 31038492
DOI: 10.1039/c9cc01947b

Abstract

We report a new mono-armed pillar[5]arene with the amino-substituent self-included in the pillarene cavity, which can stabilize the hemiaminals and imines formed from the reaction of aliphatic amines and aldehydes as monitored by mass spectroscopy.