Metal-organic frameworks for aquatic arsenic removal

Abstract

Effective remediation of arsenic contaminated water remains a critical task from the environmental perspective, owing to the harmful effects of arsenic on human health and the environment. Recently, highly porous metal-organic frameworks (MOFs) with excellent chemical stability and abundant functional groups represent a significant new addition to the area of capturing aquatic arsenic pollutants. This review focuses on the development of MOF-based materials for the efficient removal of toxic arsenic species from aqueous solutions. Aspects related to the materials' characteristics, application performance and interaction mechanisms are systematically studied, referencing the macroscopic experimental behaviors and microscopic spectroscopy analyses. The properties of various MOF-based materials are assessed and compared with those of other conventionally used materials. At last, insights and perspectives are suggested in terms of future research directions and development challenges. Overall, this class of materials demonstrates a promising potential for aquatic arsenic removal, and with a proper up-scaling development might it be used for practical applications in the near future.

Keywords: Adsorbents; Arsenic; Decontamination; MOFs; Water treatment.