Identification and characterisation of odorants in a squishy toy using gas chromatography-mass spectrometry/olfactometry after thermal extraction

Anal Bioanal Chem. 2019 Jul;411(17):3757-3761. doi: 10.1007/s00216-019-01860-9. Epub 2019 May 11.

Abstract

Soft, squashable toys known as squishies have become increasingly popular amongst children. In this study, one such toy was evaluated sensorially by a trained panel and analytically using gas chromatography-mass spectrometry/olfactometry (GC-MS/O) after thermal extraction of the sample. Sensory analysis revealed the presence of an intense and unpleasant odour exhibited by the sample. The smell was dominated by almond- and inflatable swimming aid-like, as well as malty and glue-like notes, but also pleasant odours that were described as caramel-like and coconut-like. GC-MS/O analysis identified 2-butoxyethanol, cyclohexanone, γ-nonalactone, and ethyl maltol as being the main causative substances for the overall odour of the product. The data additionally indicated that the pleasant smelling substances γ-nonalactone (coconut-like smell) and ethyl maltol (caramel-like smell) were intentionally added by the manufacturer to mask the unpleasant odour of the solvents.

Keywords: Gas chromatography olfactometry (GC-O); Off-odour; Plastic; Products of daily use; Toys.

MeSH terms

  • Gas Chromatography-Mass Spectrometry / methods*
  • Odorants / analysis*
  • Olfactometry / methods*
  • Play and Playthings*
  • Solvents / analysis

Substances

  • Solvents