Solvent Degradation and Polymerization Shrinkage Reduction of Resin Composites Using Isobornyl Methacrylate

Braz Dent J. 2019 Jun;30(3):272-278. doi: 10.1590/0103-6440201802525. Epub 2019 Jun 3.

Abstract

The aim of this study was to use the isobornyl methacrylate (IBOMA) as a combining or substituent diluent monomer in the resin matrix of dental resin composites. Thus, the resin matrix was formulated with 60 wt% of BisGMA and 40 wt% of diluent monomers. TEGDMA as the only diluent monomer was used as control with 40 wt%, while total substitution of TEGDMA was done with 40 wt% of IBOMA. The combination of IBOMA and TEGDMA was done with 20 wt% of each monomer. To the resin matrix, 65 wt% of filler particles was added. Degree of conversion (DC) using FT-IR, flexural strength (FS), flexural modulus (FM), polymerization shrinkage by gap formation (GF), Knoop hardness (KH) and solvent degradation (SD) were evaluated. Data were analyzed using ANOVA and Tukey's test (α=0.05; b=0.2). The results showed that reducing or substituting TEGDMA using IBOMA did not affect the DC (0.085), FS (p=0.886) or FM (p=0.414). Also, when IBOMA was used, lower GF was found in comparison to the control containing only TEGDMA as the diluent monomer (p=0.032). However, even though all composites presented reduction in KH during the SD test, the combination of IBOMA and TEGDMA showed similar reduction in KHN in comparison to the control group (p=0.001), while the total substitution of TEGDMA with IBOMA decreased KHN after SD (p=0.041). Thus, the combination of IBOMA and TEGDMA seem to reduce SD and GF without affecting the properties of resin composites.

MeSH terms

  • Bisphenol A-Glycidyl Methacrylate
  • Composite Resins*
  • Materials Testing
  • Methacrylates*
  • Polyethylene Glycols
  • Polymerization
  • Polymethacrylic Acids
  • Solvents
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Composite Resins
  • Methacrylates
  • Polymethacrylic Acids
  • Solvents
  • Polyethylene Glycols
  • Bisphenol A-Glycidyl Methacrylate