A Water-Stable Terbium(III)-Organic Framework as a Chemosensor for Inorganic Ions, Nitro-Containing Compounds and Antibiotics in Aqueous Solutions

Abstract

Effective detection of organic/inorganic pollutants, such as antibiotics, nitro-compounds, excessive Fe³⁺ and MnO₄ ^- , is crucial for human health and environmental protection. Here, a new terbium(III)-organic framework, namely [Tb(TATAB)(H₂ O)]⋅2H₂ O (Tb-MOF, H₃ TATAB=4,4',4''-s-triazine-1,3,5-triyltri-m-aminobenzoic acid), was assembled and characterized. The Tb-MOF exhibits a water-stable 3D bnn framework. Due to the existence of competitive absorption, Tb-MOF has a high selectivity for detecting Fe³⁺ , MnO₄ ^- , 4-nirophenol and nitroimidazole (ronidazole, metronidazole, dimetridazole, ornidazole) in aqueous through luminescent quenching. The results suggest that Tb-MOF is a simple and reliable reagent with multiple sensor responses in practical applications. To the best of our knowledge, this work represents the first Tb^III -based MOF as an efficient fluorescent sensor for detecting metal ions, inorganic anions, nitro-compounds, and antibiotics simultaneously.

Keywords: antibiotics; metal ions; metal-organic frameworks; nitroaromatic explosives; sensing.