Abstract
A straightforward method for the preparation of non-K region fused phosphorus- and nitrogen-containing (PN)-heterocyclic pyrenes has been accomplished. Their structural, photophysical, and electrochemical properties have been fully investigated. The described compounds exhibit intriguing redox properties and show strong photoluminescence with a wide range of tunable emission colors, with λem ranging from blue at 459 nm to red at 622 nm in CH2Cl2 solution.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Crystallography, X-Ray
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Cyclization
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Density Functional Theory
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Electrochemical Techniques
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Fluorescence
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Luminescence
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Molecular Probes / chemistry
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Molecular Structure
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Nitrogen / chemistry
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Oxidation-Reduction
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Phosphorus / chemistry
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Pyrenes / chemical synthesis
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Pyrenes / chemistry*
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Quantum Theory
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Solvents / chemistry
Substances
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Molecular Probes
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Pyrenes
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Solvents
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Phosphorus
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Nitrogen