Crystal structure of (N, N'-ethyl-enebis{3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]-4-oxo-pentan-2-iminato})copper(II)-3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]pentane-2,4-dione (1/1)

Jan Marten; Wilhelm Seichter; Edwin Weber

doi:10.1107/S2056989019005838

Crystal structure of (N, N'-ethyl-enebis{3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]-4-oxo-pentan-2-iminato})copper(II)-3-[2-(3-nitro-phen-yl)hydrazin-1-yl-idene]pentane-2,4-dione (1/1)

Acta Crystallogr E Crystallogr Commun. 2019 May 21;75(Pt 6):834-837. doi: 10.1107/S2056989019005838. eCollection 2019 Jun 1.

Authors

Jan Marten¹, Wilhelm Seichter¹, Edwin Weber¹

Affiliation

¹ TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen, Germany.

Abstract

In the title 1:1 co-crystal, [Cu(C₂₄H₂₄N₈O₆)]·C₁₁H₁₁N₃O₄, each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol-ecules of the Cu^II complex are connected via C-H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra-molecular networks. Mol-ecules of the aryl-hydrazone component are linked by C-H⋯O inter-actions into zigzag strands showing no inter-strand association.

Keywords: CuII chelate; C—H⋯O hydrogen bonding; arylhydrazone; crystal structure; molecular layer formation; two-component crystal.