Synthesis of iron oxides impregnated green adsorbent from sugarcane bagasse: Characterization and evaluation of adsorption efficiency

J Environ Manage. 2019 Nov 1:249:109323. doi: 10.1016/j.jenvman.2019.109323. Epub 2019 Aug 7.

Abstract

This present research aims to synthesize and investigate the adsorption potential of sugarcane bagasse (SCB) impregnated with iron oxide (Fe3O4) for dye removal. The surface morphology and functional groups of the newly developed adsorbent (ISCB) were studied using Scanning Electron Microscopy/Energy-dispersive X-ray spectroscopy (SEM/EDX), Fourier transforms infrared spectroscopy (FTIR), and X-ray powder diffraction (XRD) analysis. The effects of the operating parameters, including initial dye concentration, adsorbent dosage, contact time and initial pH of the dye solution on the adsorption efficiency were investigated to identify an optimal condition. The characterization of SEM-EDX and FTIR analyses shows that ISCB has a porous structure and carbon-containing functional groups. The adsorption result revealed that ISCB removed 93.7% of dye, 88.8% of color and had a dye adsorption capacity of 7.2 mg/g within 6 h of contact time using 0.7 g/L of ISCB at pH 8.4. The result obtained fitted well for Langmuir isotherms, and adsorption process followed the pseudo-second-order kinetic model. In conclusion, this study proved that ISCB has the potential to be used as an effective and low-cost adsorbent to remove dyes from wastewater.

Keywords: Adsorbent; Agro waste; Dye removal; Iron oxide; SEM-EDX; Sugarcane bagasse.

MeSH terms

  • Adsorption
  • Cellulose
  • Ferric Compounds
  • Kinetics
  • Saccharum*
  • Spectroscopy, Fourier Transform Infrared
  • Water Pollutants, Chemical*

Substances

  • Ferric Compounds
  • Water Pollutants, Chemical
  • ferric oxide
  • Cellulose
  • bagasse