Biodegradation kinetic modeling of oxo-biodegradable polypropylene/polylactide/nanoclay blends and composites under controlled composting conditions

Abstract

Polypropylene/polylactide/nanoclay blend/composite films with/without pro-oxidants/compatibilizer were prepared and aerobically degraded to measure the CO₂ evolution under controlled composting conditions as per ASTM D 5338. A first-order Komilis model in series with a flat lag phase was postulated involving two stages; hydrolysis of solid carbon followed by its rapid mineralization. The first, rate-limiting stage further comprised of three possible parallel paths: the solid hydrolysis of readily, moderately, and slowly hydrolyzable carbon fractions. The model parameters were computed after correlating with the experimental data using nonlinear regression analysis. The results of the model characteristic parameters, un-degraded/hydrolyzable/mineralisable-intermediate carbon kinetics, and degradation curves exhibit two distinct kinetic regimes. The first regime comprising of slowly and moderately hydrolyzable carbon is shown by the first four films without pro-oxidants. This causes low degradability and degradation rate. The second regime comprising of the readily and moderately hydrolyzable carbon is shown by another four films containing pro-oxidants. They exhibit relatively high degradability and degradation rate, which peaks at around 11-14th day in the range of 0.219-0.268% per day. The values of their moderately hydrolyzable carbon fractions and the corresponding hydrolysis rates are significantly higher than that of the first regime. For the first regime, the degradability and degradation rate decreases with increase in the slowly hydrolyzable carbon impervious to microbial attack. Their degradation rate profiles show an absence of growth phase due to the absence of readily hydrolyzable carbon. The rate decreases monotonously starting from the maximum value ranging from 0.043 to 0.180% per day. The approach presented can also be implemented to model and design equipment for other waste biodegradation systems.

Keywords: Biodegradation; Blend; Kinetic modeling; Polylactide; Polypropylene; Pro-oxidant.