Enhanced Light Harvesting in Photovoltaic Devices Using an Edge-Located One-Dimensional Grating Polydimethylsiloxane Membrane

ACS Appl Mater Interfaces. 2019 Oct 2;11(39):36020-36026. doi: 10.1021/acsami.9b09377. Epub 2019 Sep 18.

Abstract

In streamlined multipurpose applications for light management and protection, encapsulants are merged with photonic crystal structures into solar modules. We present an edge-located 1D grating, attachable polymer on the top of a photovoltaic module to provide a strategy for capturing solar light and improving cell efficiency. Large-area solar arrays suffer from space utilization problems due to nonactive area. The introduction of periodically patterned gratings with specific geometric range is highly preferred to redirect the light toward photovoltaic active areas. To realize optimized broadband light diffraction for solar devices, the theoretical analysis of one-dimensional line patterned diffraction gratings was performed through wave-optic-based simulation. Based on the experimental results, the replica molding-based patterning method was adopted to fabricate the grating polymer for low-cost thin-film production. Also, we demonstrated enhanced light collection by grating patterned encapsulants with improved current density in comparison to the performance of a flat surface.

Keywords: diffraction; encapsulant; grating structure; light harvesting; photovoltaic device; polydimethylsiloxane; soft imprint lithography.