Effects of residual carbon materials on the disinfection byproduct formation in artificial and natural waters

Abstract

As the effective adsorbents, carbon materials (CMs) are typically used in the removal of disinfection byproduct (DBP) precursors during the water treatment by adding CMs before disinfection procedure. However, after the separation of CMs from the treated water by flocculation, sedimentation, and filtration, a small amount of loaded activated carbon could be released into the water treatment system and affect the DBP formation in the following disinfection. In this study, three CMs, including coal-made activated carbon (CAC), sawdust charcoal (SCC), and hydroxylated multiwall carbon nanotubes (OH-MWCNT), were used to explore the effects of residual CMs in the formation of DBPs. The results indicated that some DBP precursors could be irreversibly adsorbed into the pore structure of CMs and hardly to be extracted and determined, then affected the DBP formation in the water system. In the chlorination process of surface water samples, CMs have similar effects on the formation of DBPs. However, given that water samples contain a variety of complex substances, the effects of residual CMs on the formation of DBPs were also slightly changed.

Keywords: Adsorption; Carbon materials; Chlorination; Disinfection byproducts.