Impaired metabolism of kynurenine and its metabolites in CSF of parkinson's disease

Neurosci Lett. 2020 Jan 1:714:134576. doi: 10.1016/j.neulet.2019.134576. Epub 2019 Oct 22.

Abstract

Aim: The kynurenine (KYN) pathway plays an important role in degrading molecules responsible for oxidative stress in the central nervous system (CNS), but can also have neurotoxic effects. Both 3-hydroxykynurenine (3-HK) and quinolinic acid are neurotoxic metabolites produced from this pathway. In Parkinson's disease (PD), oxidative stress is suspected to represent a key pathogenic mechanism. This study aimed to investigate the function of the KYN pathway and interactions between oxidative stress and neuroinflammation in PD.

Methods: Participants comprised 20 patients with PD and 13 controls. Cerebrospinal fluid (CSF) levels of KYN and 3-HK were measured using high-performance liquid chromatography coupled with an electrochemical detector. CSF levels of tumor necrosis factor (TNF)-α, interleukin (IL)-1β, IL-6, and interferon (IFN)-γ were measured with an enzyme-linked immunosorbent assay, and results were statistically compared between PD patients and controls.

Results: Median CSF levels of KYN and 3-HK were 49.0 nM and 4.25 nM in PD and 30.5 nM and 1.55 nM in controls, respectively, showing significantly higher levels in PD (p < 0.05). CSF levels of measured cytokines showed that TNF-α and IL-1β were significantly higher in PD patients than in controls. No positive correlation between 3-HK and TNF-α was seen in PD.

Conclusion: Dysfunction of the KYN pathway may induce oxidative stress in the CNS in PD, and may also induce cytokine-mediated neuroinflammation. Functional amelioration of the KYN pathway may facilitate modification of neurodegenerative processes in PD.

Keywords: Kynurenine pathway; Neuroinflammation; Oxidative stress; Parkinson’s disease.

MeSH terms

  • Aged
  • Case-Control Studies
  • Cytokines / cerebrospinal fluid*
  • Female
  • Humans
  • Inflammation / cerebrospinal fluid*
  • Inflammation / metabolism
  • Interferon-gamma / cerebrospinal fluid
  • Interleukin-1beta / cerebrospinal fluid
  • Interleukin-6 / cerebrospinal fluid
  • Kynurenine / analogs & derivatives*
  • Kynurenine / cerebrospinal fluid*
  • Kynurenine / metabolism
  • Male
  • Metabolic Networks and Pathways
  • Middle Aged
  • Oxidative Stress*
  • Parkinson Disease / cerebrospinal fluid*
  • Parkinson Disease / metabolism
  • Tumor Necrosis Factor-alpha / cerebrospinal fluid

Substances

  • Cytokines
  • IFNG protein, human
  • IL1B protein, human
  • IL6 protein, human
  • Interleukin-1beta
  • Interleukin-6
  • TNF protein, human
  • Tumor Necrosis Factor-alpha
  • 3-hydroxykynurenine
  • Kynurenine
  • Interferon-gamma