Nuclear energy is clean, reliable, and competitive with many useful applications, among which power generation is the most important as it can gradually replace fossil fuels and avoid massive pollution of environment. A by-product resulting from utilization of nuclear energy in both power generation and other applications, such as in medicine, industry, agriculture, and research, is nuclear waste. Safe and effective management of nuclear waste is crucial to ensure sustainable utilization of nuclear energy. Nuclear waste must be processed to make it safe for storage, transportation, and final disposal, which includes its conditioning, so it is immobilized and packaged before storage and disposal. Immobilization of waste radionuclides in durable wasteform materials provides the most important barrier to contribute to the overall performance of any storage and/or disposal system. Materials for nuclear waste immobilization are thus at the core of multibarrier systems of isolation of radioactive waste from environment aimed to ensure long term safety of storage and disposal. This Special Issue analyzes the materials currently used as well as novel materials for nuclear waste immobilization, including technological approaches utilized in nuclear waste conditioning pursuing to ensure efficiency and long-term safety of storage and disposal systems. It focuses on advanced cementitious materials, geopolymers, glasses, glass composite materials, and ceramics developed and used in nuclear waste immobilization, with the performance of such materials of utmost importance. The book outlines recent advances in nuclear wasteform materials including glasses, ceramics, cements, and spent nuclear fuel. It focuses on durability aspects and contains data on performance of nuclear wasteforms as well as expected behavior in a disposal environment.
Keywords: ceramics; conditioning; durability; glass; glass composite materials; immobilisation; nuclear waste; spent nuclear fuel; vitrification; wasteforms.