High Stability and Strong Fluorescence of Carbon Nanodots as Nanosensor for Hg2+ in Environmental Waters

Bull Environ Contam Toxicol. 2020 Jan;104(1):57-63. doi: 10.1007/s00128-019-02753-4. Epub 2019 Nov 25.

Abstract

Pollution of toxic heavy-metal ions such as mercury ions (Hg2+) is well known to severely threaten ecological environment and human health. Correspondingly, development of a fast and sensitive method for detecting heavy-metal ions is urgently needed and has been received widespread attention in recent years. In this study, carbon nanodots (CDs) with strong blue fluorescence were synthesized by a microwave-assisted hydrothermal method. The as-prepared blue fluorescent CDs not only have excellent stability (e.g. photostability, salt stability and pH stability), but also have extremely high selectivity and sensitivity for probing Hg2+ via fluorescence quenching. Specifically, fluorescence of CDs is gradually quenched along with the increase in Hg2+ concentration, and a low concentration of Hg2+ can be identified (with low detection limit, 15 nM). Therefore, the novel fluorescent CDs could be developed for detecting Hg2+ in aqueous conditions, and have great potential for fast probing Hg2+ in environmental samples.

Keywords: Environmental waters; Fluorescent carbon nanodots; Mercury ions; Nanosensor; Selective detection.

MeSH terms

  • Environmental Monitoring / instrumentation
  • Environmental Monitoring / methods*
  • Fluorescent Dyes / chemistry*
  • Humans
  • Limit of Detection
  • Mercury / analysis*
  • Nanotubes, Carbon / chemistry*
  • Spectrometry, Fluorescence / methods
  • Water Pollutants, Chemical / analysis*

Substances

  • Fluorescent Dyes
  • Nanotubes, Carbon
  • Water Pollutants, Chemical
  • Mercury