Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

Chem Commun (Camb). 2020 Mar 28;56(25):3681-3684. doi: 10.1039/c9cc09638h. Epub 2020 Mar 2.

Abstract

Utilising normal incidence X-ray standing waves we rigourously scrutinise the "inverted model" as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). We demonstrate that the iminic N atoms are anchored at near-bridge adsorption sites on the surface displaced laterally by 1.1 ± 0.2 Å in excellent agreement with previously published calculations.