Synergistic adsorptions of Na2CO3 and Na2SiO3 on calcium minerals revealed by spectroscopic and ab initio molecular dynamics studies

Abstract

The synergistic effects between sodium silicate (Na₂SiO₃) and sodium carbonate (Na₂CO₃) adsorbed on mineral surfaces are not yet understood, making it impossible to finely tune their respective amounts in various industrial processes. In order to unravel this phenomenon, diffuse reflectance infrared Fourier transform and X-ray photoelectron spectroscopies were combined with ab initio molecular dynamics to investigate the adsorption of Na₂SiO₃ onto bare and carbonated fluorite (CaF₂), an archetypal calcium mineral. Both experimental and theoretical results proved that Na₂CO₃ adsorbs onto CaF₂ with a high affinity and forms a layer of Na₂CO₃ on the surface. Besides, at low Na₂SiO₃ concentration, silica mainly physisorbs in a monomeric protonated form, Si(OH)₄, while at larger concentration, significant amounts of polymerised and deprotonated forms are identified. Prior surface carbonation induces an acid-base reaction on the surface, which results in the formation of the basic forms of the monomers and the dimers, i.e. SiO(OH)₃ ^- and Si₂O₃(OH)₄ ^2-, even at low coverage. Their adsorption is highly favoured compared to the acid forms, which explains the synergistic effects observed when Na₂SiO₃ is used after Na₂CO₃. The formation of the basic form on the bare surface is observed only by increasing the surface coverage to 100%. Hence, when Na₂CO₃ is used during a separation process, lower Na₂SiO₃ concentrations are needed to obtain the same effect as with lone Na₂SiO₃ in the separation process.