The synergistic action of anodic oxidation using boron-doped diamond and low-frequency ultrasound in different water matrices and operating conditions for the decomposition of the emerging contaminant propyl paraben was investigated. The degree of synergy was found to decrease with an increase in current in the range 1.25-6.25 mA/cm2 or the ultrasound power until 36 W/L, where a further decrease was observed. Despite the fact that the increased propyl paraben concentration decreased the observed kinetic constant for both the separated and the hybrid process, the degree of synergy was increased from 37.3 to 43.4% for 0.5 and 2 mg/L propyl paraben, respectively. Bicarbonates (100-250 mg/L) or humic acid (10-20 mg/L) enhanced the synergy significantly by up to 55.8%, due to the higher demand for reactive oxygen species. The presence of chloride ions decreased the observed synergistic action in comparison with ultrapure water, possibly due to the electro-generation of active chlorine that diffuses to the bulk solution. The same behavior was observed with the secondary effluent that contained almost 68 mg/L of chlorides. The efficiency was favored in a neutral medium, while the hybrid process was delayed in alkaline conditions.
Keywords: electrochemical oxidation; parabens; synergy; ultrasound; water matrices.