Tidal groundwater dynamics and hydrochemistry can play important roles in influencing nearshore ecological and environmental systems. However, the potential relationship between the groundwater dynamics and the hydrochemical characteristics was not well understood. In this study, we conducted an integrated investigation by field work and numerical simulations to explore the potential effect of tidal groundwater dynamics on hydrochemistry in an intertidal mudflat in Daya Bay, China. The time series of groundwater level were monitored over a spring-neap tidal cycle along a 200-m-long intertidal transect, which had a mud-sand-layered aquifer. The shallow groundwater samples were collected to analyze the spatial distributions of hydrochemical characteristics, including major ions (Na+, K+, Ca2+, Mg2+, SO42-, HCO3-, and Cl-), heavy metals (As and Cu), and short-lived radium isotopes (223Ra and 224Ra). The groundwater transport process along the transect was simulated for understanding the groundwater flow field and quantifying the groundwater-seawater exchange rates across the water-sediment interface. The integrated results indicated that the seawater-groundwater interactions play a great influence on the groundwater hydrochemistry. For example, the major ions showed various degrees of enrichment and loss, such as losses of SO42- due to microbial sulfate reduction, and enrichment of HCO3-, Ca2+, and Mg2+ under the water-rock interactions. Heavy metals were transported by groundwater and accumulated in the intertidal sediments. In addition, there was a negative correlation between short-lived radium isotope activities and oxidation-reduction potential. However, the relationship between seawater-groundwater exchange rates and the short-lived radium isotope activities was not significant.
Keywords: Coastal groundwater; Heavy metals; Numerical simulation; Radium activity; Seawater-groundwater interactions.