A new approach to dispersing and stabilizing graphene in aqueous nanofluids of enhanced efficiency of energy-systems

Sci Rep. 2020 May 7;10(1):7707. doi: 10.1038/s41598-020-64600-5.

Abstract

Owing to its severe hydrophobicity, graphene (G) as on dispersed in a fluid usually deposits therein after a short interval of time. Understanding the G-behavior and the factors affecting its deposition could pave a way for creating a substantially stable nanofluid (NF). In this work, a novel method of stabilizing a G-NF is described with selective examples. The results can be extended to develop the science and technology of G-NFs in general. Electrohydrodynamic forces are used as a controlling factor in the presence of magnetic nanoparticles (MNPs). Contrary to common chemical methods employed for preparing G-NFs, which depend on establishing bonds between the components, the physical method introduced in this article could be used as a novel approach not only to dispersing G in a fluid carrier but also to resolve the common problems originating from utilizing such chemical methods as increasing thermal resistance through adding various types of surfactants. The effects of various factors on the stability of the G-NFs are described. By increasing 50%, 100% and 170% of G, the G sitting rate increased by 43%, 82%, and 109%, respectively. With the addition of one, two and three layers to a G-monolayer, the G sitting rate grew by 77%, 153%, and 263%, respectively. Further, the G-behavior in the presence of MNPs and varied intensive electric fields were studied to optimize an electric field that could stabilize a single-layer G sheet in aqueous NFs. Adding MNPs promptly stabilizes a water/ethylene glycol/G NF in an applied electric field of 0.05 V/Å.