Rational regulation of transition metals in polyoxometalate hybrids without noble metal assistance for efficient light-driven H 2 production

Chem Commun (Camb). 2020 Jul 4;56(52):7199-7202. doi: 10.1039/d0cc00846j. Epub 2020 May 29.


Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 μmol g-1 h-1, which outperform all known POM-based metal-organic photocatalysts.