Juncus effusus fiber-based cellulose cigarette filter with 3D hierarchically porous structure for removal of PAHs from mainstream smoke

Abstract

Polycyclic aromatic hydrocarbons (PAHs) from cigarettes are one of the main pollutants affecting public health. Herein, a cellulose cigarette filter with three-dimensional (3D) hierarchically porous structure was fabricated using a natural cellulose Juncus effusus (JE) fiber, whose pore size was well controlled by biocompatible polyvinylpyrrolidone (PVP) using a simple dip-dry method. The adsorption capacity and mechanism of the PVP-JE filter tips (PJF) against PAHs were investigated in detail. Compared with conventional cellulose acetate filter tips (CAF), the cellulose PJF were superior at filtering and adsorbing of PAHs from mainstream smoke with the removal efficiency of 61.79 %, which was 22.57 % higher than that of CAF (39.22 %). The ternary structures including polymer filter membrane, 3D network, and interconnected channels were demonstrated as the main roles for highly effective removal of PAHs. The JE-based cellulose cigarette filter can be a promising candidature to broaden the application range of polysaccharide in pollutant elimination.

Keywords: 3D porous structure; Cellulose; Cigarette filter; Juncus effusus; Polycyclic aromatic hydrocarbons.