Sugarcane bagasse is a significant renewable energy source for the sugar and bioethanol industries. Bagasse ash is the waste from the combustion process and is mostly disposed of as landfill. Only a small quantity of bagasse ash is utilized as pozzolan in concrete, and a considerable quantity is left unused due to its high carbon and crystallite content. Generally, bagasse ash is rich in silica (SiO2), and it is thus an alternative source for silica extraction. In this paper, a low-energy and low-chemical consumption method is proposed to obtain silica from bagasse ash using alkali extraction and acid precipitation. The physical and chemical properties of the extracted silica are described. A silica yield of 80% and moisture absorption of 73% were achieved. The silica had amorphous phases and was light gray in color owing to the presence of carbon from incomplete combustion. Bagasse silica was used as an extender filler in an expensive photochromic pigment to increase the bulk volume. It was found that a pigment-to-silica mass ratio up to 1:10 could be used for thick-layer painting. However, a ratio of up to 1:3 is recommended for thin-layer screen-printing on fabrics. The bagasse ash silica-pigment blends have very good color fastness when washing; however, frequent aggressive washing should be avoided.