Solar-driven carbon dioxide (CO2) conversion to fuels and high-value chemicals can contribute to the better utilization of renewable energy sources. Photosynthetic (PS), photocatalytic (PC), photoelectrochemical (PEC), and photovoltaic plus electrochemical (PV+EC) approaches are intensively studied strategies. We aimed to compare the performance of these approaches using unified metrics and to highlight representative studies with outstanding performance in a given aspect. Most importantly, a statistical analysis was carried out to compare the differences in activity, selectivity, and durability of the various approaches, and the underlying causes are discussed in detail. Several interesting trends were found: (i) Only the minority of the studies present comprehensive metrics. (ii) The CO2 reduction products and their relative amount vary across the different approaches. (iii) Only the PV+EC approach is likely to lead to industrial technologies in the midterm future. Last, a brief perspective on new directions is given to stimulate discussion and future research activity.
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