Enhanced electrochemical performance by nickel-iron layered double hydroxides (LDH) coated on Fe3O4 as a cathode catalyst for single-chamber microbial fuel cells

Abstract

The improvement of cathode performance has always been the bottleneck and research hot spot for microbial fuel cells (MFCs). An Fe₃O₄@NiFe-LDH composite with a nanoscale core-shell structure containing an Fe₃O₄ magnetic core and a layered double hydroxide (LDH) shell was prepared by the hydrothermal method. The Fe₃O₄@NiFe-LDH was characterized by FT-IR, XRD, SEM and EDS. The characterization results showed that the composite had a unique cauliflower-like nanoflake structure and special pore size distribution, which greatly improved the ORR performance. Moreover, the use of the synthesized Fe₃O₄@NiFe-LDH core-shell structure as an electrode in an MFC was characterized by CV and LSV, which showed that the Fe₃O₄@NiFe-LDH exhibited excellent ORR catalytic properties. The voltage output of the Fe₃O₄@NiFe-LDH MFC was maintained at approximately 0.39 V, with insignificant variations over 110 h. The maximum power density was 211.40 ± 2.27 mW/m², which was 34 times that of the blank control group MFC and was caused by the many electroactive sites, good rate capability and remarkable cycling stability of LDH. This study provides the possibility for using Fe3O4@NiFe-LDH in cathodes to operate continuously and at low cost in fuel cells.

Keywords: Fe(3)O(4); Layered double hydroxide (LDH); Microbial fuel cell; Oxygen reduction reaction.