Slight Deuterium Enrichment in Water Acts as an Antioxidant: Is Deuterium a Cell Growth Regulator?

Mol Cell Proteomics. 2020 Nov;19(11):1790-1804. doi: 10.1074/mcp.RA120.002231. Epub 2020 Aug 7.

Abstract

Small admixtures in water, e.g. of metal ions, often act as cell growth regulators. Here we report that enrichment of deuterium content in water, normally found at 8 mm concentration, two-three folds increases cell proliferation and lowers the oxidative stress level as well. Acting as an anti-oxidant, deuterium-enriched water prevents the toxic effect of such oxidative agents as hydrogen peroxide and auranofin. This action is opposite to that of deuterium depletion that is known to suppress cell growth and induce oxidative stress in mitochondria. We thus hypothesize that deuterium may be a natural cell growth regulator that controls mitochondrial oxidation-reduction balance. Because growth acceleration is reduced approximately by half by addition to water a minute amount (0.15%) of 18O isotope, at least part of the deuterium effect on cell growth can be explained by the isotopic resonance phenomenon. A slight (≈2-fold) enrichment of deuterium in water accelerates human cell growth. Quantitative MS based proteomics determined changes in protein abundances and redox states and found that deuterium-enriched water acts mainly through decreasing ROS production in mitochondria. This action is opposite to that of deuterium depletion that suppresses cell growth by inducing oxidative stress. Thus deuterium may be a natural cell growth regulator that controls mitochondrial oxidation-reduction balance. The role of isotopic resonance in this effect was validated by further experiments on bacteria.

Keywords: Mass spectrometry; antioxidant; cell growth regulator; chemoproteomics; deuterium effect; deuterium-enriched water; oxidation-reduction balance; oxidative stress; quantification; redox balance; thiol redox chemistry.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antioxidants / pharmacology*
  • Cell Line, Tumor
  • Cell Proliferation / drug effects*
  • Cell Survival / drug effects
  • Deuterium / metabolism*
  • Escherichia coli / drug effects
  • Humans
  • Metabolic Networks and Pathways / drug effects
  • Mitochondria / metabolism
  • Oxidation-Reduction
  • Oxidative Stress / drug effects*
  • Principal Component Analysis
  • Protein Interaction Maps
  • Proteome / metabolism*
  • Proteomics
  • Reactive Oxygen Species / metabolism
  • Tandem Mass Spectrometry
  • Water / pharmacology*

Substances

  • Antioxidants
  • Proteome
  • Reactive Oxygen Species
  • Water
  • Deuterium