Towards Upscaling of La5.5WO11.25-δ Manufacture for Plasma Spraying-Thin Film Coated Hydrogen Permeable Membranes

Membranes (Basel). 2020 Aug 19;10(9):192. doi: 10.3390/membranes10090192.


Lanthanum tungstate (La6WO12) is a promising material for the development of hydrogen separation membranes, proton ceramic electrolyzer cells and protonic ceramic fuel cells due to its interesting transport properties and stability under different operation conditions. In order to improve the hydrogen transport through the La6WO12 membranes, thin membranes should be manufactured. This work is based on the industrial production of La5.5WO11.25-δ (LWO) powder by spray drying and the manufacturing of thin membranes by low-pressure plasma spraying (LPPS-TF) technique. LPPS-TF allows the production of dense thin films of high quality in an industrial scale. The powders produced by spray drying were morphological and electrochemically characterized. Hydrogen permeation fluxes of a membrane manufactured with these powders were evaluated and fluxes are similar to those reported previously for LWO powder produced in the lab scale. Finally, the transport properties of LWO thin films deposited on Al2O3 indicate that LPPS-TF produces high-quality LWO films with potential for integration in different applications.

Keywords: H2 separation; ceramic protonic conductors; lanthanum tungstate; low-pressure plasma spraying (LPPS-TF); membrane reactors.