Accurately-controlled recovery and regeneration of protic ionic liquid after Ionosolv pretreatment via bipolar membrane electrodialysis with ultrafiltration

Abstract

Efficient recovery and regeneration of ionic liquid is significant for industrial Ionosolv pretreatment. Complicated electrolyte composition restricts the scale-up recovery and application of protic ionic liquid such as triethylammonium hydrogen sulfate [TEA][HSO₄] in biomass-related research. Recovery of [TEA][HSO₄] after Ionosolv pretreatment for miscanthus powder was studied using bipolar membrane electrodialysis (BMED) assisted with ultrafiltration (UF) by the divisional recovery of TEA⁺ as TEA and recovery of SO₄^2- as H₂SO₄ in different BMED compartments. Hence accurately-controlled regeneration of [TEA][HSO₄] could be realized. Influence of current density and feed concentration of BMED module was studied in detail. In this study, the highest recovery ratio for TEA⁺ and SO₄^2- reached 93.7% and 96.4%. The lowest energy consumption of specific [TEA][HSO₄] recovery was about 6.2 kwh/kg. Insight gained from this study suggests a potentially industrial methodology for complicated protic ionic liquid recovery after biomass processing.

Keywords: Membrane; Protic ionic liquid; Recovery; Regeneration.