Adsorptive removal of hazardous organics from water and fuel with functionalized metal-organic frameworks: Contribution of functional groups

Abstract

The purification of contaminated water and fuel is very important for our sustainability. Adsorptive removal has attracted significant attention because of possible applications in industry and the rapid development of metal-organic frameworks (MOFs), which can be competitive adsorbents. In this review, the possible/competitive purification of water (contaminated with organics) and fuel (composed of S- and N-Containing compounds) via adsorption using MOFs, especially those with various functional groups (FGs), will be discussed. The contribution of FGs such as -OH, -COOH, -SO₃H, -NH₂, and -NH₃⁺ to adsorption/purification will be analyzed in detail, not only to understand the plausible adsorption mechanism but also to utilize specific FGs in adsorption. Moreover, methods for introducing FGs onto MOFs will be summarized. Finally, the prospects for both adsorption/removal and emerging fields will be suggested. Studies for practical applications in industry with shaped MOFs from inexpensive route will be important. The solution pH should be considered for the adsorption of aqueous solution. Applications of MOFs in other fields like storage/delivery and enrichment of analytes might be deeply studied.

Keywords: Adsorption; Fuel; Functional groups; Mechanisms; Metal-organic frameworks; Removal; Water.