Abstract
Arachidonate 15-lipoxygenase was purified from human eosinophil-enriched leukocytes after showing that 15-lipoxygenase activity was 100-fold greater in eosinophils than in neutrophils. Partial purification was achieved using ammonium sulfate precipitation, cation-exchange and hydrophobic-interaction chromatography. New evidence is presented suggesting that 15-lipoxygenase has electrostatic and hydrophobic properties distinct from 5-lipoxygenase. In addition, ATP is shown to inhibit, and phosphatidylcholine is shown to stimulate, 15-lipoxygenase, suggesting a regulatory role for these compounds in the lipoxygenation of arachidonic acid.
Publication types
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Comparative Study
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Adenosine Triphosphate / pharmacology
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Arachidonate 15-Lipoxygenase / blood*
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Arachidonate 5-Lipoxygenase / blood
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Arachidonate Lipoxygenases / blood*
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Chromatography
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Chromatography, Ion Exchange
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Eosinophils / enzymology*
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Fractional Precipitation
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Humans
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Hydrogen-Ion Concentration
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Hydroxyeicosatetraenoic Acids / blood
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Leukocytes / enzymology*
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Lipoxygenase Inhibitors
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Neutrophils / enzymology
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Phosphatidylcholines / pharmacology
Substances
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Hydroxyeicosatetraenoic Acids
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Lipoxygenase Inhibitors
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Phosphatidylcholines
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15-hydroxy-5,8,11,13-eicosatetraenoic acid
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Adenosine Triphosphate
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Arachidonate Lipoxygenases
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Arachidonate 15-Lipoxygenase
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Arachidonate 5-Lipoxygenase