Infrared spectra of hydrogen bond network in lamellar perfluorocarboxylic acid monohydrates

Urban Novak; Jože Grdadolnik

doi:10.1016/j.saa.2021.119551

Infrared spectra of hydrogen bond network in lamellar perfluorocarboxylic acid monohydrates

Spectrochim Acta A Mol Biomol Spectrosc. 2021 May 15:253:119551. doi: 10.1016/j.saa.2021.119551. Epub 2021 Feb 5.

Authors

Urban Novak¹, Jože Grdadolnik²

Affiliations

¹ National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana, Slovenia. Electronic address: urban.novak@ki.si.
² National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana, Slovenia. Electronic address: joze.grdadolnik@ki.si.

PMID: 33610100
DOI: 10.1016/j.saa.2021.119551

Abstract

The infrared spectra of the long-chain perfluorocarboxylic acid monohydrates differ markedly from those of the anhydrous dimers. Consequently, the structure of the solid perfluorocarboxylic acid monohydrates must differ from any known dimer-containing carboxylic acid crystals. Consideration of the significant features of the infrared spectra of the long-chain perfluorocarboxylic acid monohydrates, supplemented by their Raman spectra, and comparison with the spectra of auxiliary substances have led us to conclude that the rather strong neutral carboxyl-hydroxyl to water bonding can best explain the observations. The infrared spectra indicate the presence of fairly short hydrogen bonds connecting the water molecules to the carbonyl groups. In the construction of the hydrogen bonding pattern of the perfluorocarboxylic acid monohydrates, the oxalic acid dihydrate plays the key role. The striking similarity between the infrared spectra of the oxalic acid dihydrates and the perfluorocarboxylic acid monohydrates in the regions characteristic of water and OH⋯O vibration suggests that the structure of the hydrated carboxyl groups is the same in both crystals. These regions are characterized by the sharp doublet at 3539 cm^-1 and 3464 cm^-1, which is due to the H₂O ν₁ and ν₃ stretching vibrations, respectively, and the broad absorption between 3000 cm^-1 and 1500 cm^-1 with the intense band at 1970 cm^-1, both associated with the vibration of the OH⋯O group. The later peak consists of two band components at near 1980 cm^-1 and 2020 cm^-1. These band components show different behaviour when the temperature, polarization or deuteration is changed. In general, the infrared spectra of long-chain perfluorocarboxylic acids represent the system with very short hydrogen bonds connecting the water molecules to the carboxylates. This hydrogen bond pattern should be very similar to that found in the crystals of α-oxalic acid dihydrate.

Keywords: FTIR spectroscopy; OH stretching; Oxalic acid dihydrate; Perfluorated fatty acids monohydrates; Strong hydrogen bond; Trifluoroacetic acid tetrahydrate.