Production and characteristics of elemental sulfur during simultaneous nitrate and sulfide removal

Environ Sci Pollut Res Int. 2021 Jul;28(27):36226-36233. doi: 10.1007/s11356-021-13269-y. Epub 2021 Mar 9.

Abstract

The production and characteristics of elemental sulfur were examined during simultaneous sulfide and nitrate removal, with abiotic assays as control. The biotic assay showed good sulfide and nitrate removal, with the respective removal percentage of which were 90.67-96.88% and 100%. Nitrate reduction resulted in the production of nitrogen gas, while sulfate formed due to sulfide oxidation. The concentration of elemental sulfur in the effluent was greater than that in the sludge, which accounted for 73.70-86.28% of total elemental sulfur produced. Furthermore, the elemental sulfur of the effluent and sludge from the biotic assays was orthorhombic crystal S8. Elemental sulfur was normally distributed in the effluent, but its average diameter increased with the increasing influent sulfide concentration (60-300 mg S/L), where the average diameter increased from 10 (60 mg S/L) to 29 μm (300 mg S/L).

Keywords: Abiotic reactor; Anaerobic sulfide and nitrate removal; Biologically produced sulfur; Biotic reactor; Distribution; Orthorhombic crystal S8.

MeSH terms

  • Bioreactors*
  • Nitrates*
  • Oxidation-Reduction
  • Sewage
  • Sulfides
  • Sulfur

Substances

  • Nitrates
  • Sewage
  • Sulfides
  • Sulfur