We present a Mach-Zehnder interferometer assisted ring resonator configuration (MARC) to realize resonator transmission spectra with unique spectral signatures and significantly large effective free spectral ranges. Transmission spectra with unique spectral signatures are generated by changing the angular separation between the through port and the drop port waveguides of the ring resonator (RR). These spectral signatures are comprised of several distinct resonance lineshapes including Lorentzian, inverse Lorentzian and asymmetric Fano-like shapes. One of the spectral signatures generated from the MARC device is utilized for the temperature sensing measurement to demonstrate a MARC-based sensor with high Q-factor and wide measurement range.