Cross-linked FeCl3-activated seaweed carbon/MCM-41/alginate hydrogel composite for effective biosorption of bisphenol A plasticizer and basic dye from aqueous solution

Abstract

A FeCl₃-activated seaweed carbon/MCM-41/alginate hydrogel composite (ECAC/MCM-41/ ALG) cross-linked with calcium chloride (2% CaCl₂) was synthesized for the biosorption of bisphenol A (BPA) plasticizer and basic blue (BB) dye. Biosorption uptakes of BPA and BB were performed in a batch mode with varying solution pH from 3 to 11, initial sorbate concentration from 25 to 300 mg/L, reaction time from 0 to 10 h, and biosorption temperature from 30 to 50 °C. The maximum BPA and BB uptake mechanisms were fast, which occurred within contact times of 1 and 2 h with monolayer coverage capacities of 222.32 and 190.11 mg/g at 50 °C, respectively. Cyclic biosorption/desorption behavior was evaluated via an ethanol elution to evaluate the feasibility of the ECAC/MCM-41/ALG for long-term application. Results revealed the biosorption renewability for five cycles up to 80% of the newly synthesized hydrogel composite for the purification of industrial wastewater laden with emerging contaminants.

Keywords: Biosorption; Bisphenol A plasticizer; FeCl(3)-pyrolysis; Hydrogel composite; MCM-41; Seaweed.