Preparation and characterization of carboxymethylcellulose based citric acid cross-linked magnetic aerogel as an efficient dye adsorbent

Int J Biol Macromol. 2021 Jun 30:181:1030-1038. doi: 10.1016/j.ijbiomac.2021.04.078. Epub 2021 Apr 20.

Abstract

A low-cost, collectable, and efficient material is essential for adsorbing water pollution, such as dyes and heavy metal ions pollution. In this work, we proposed a novel strategy for the preparation of an efficient and collectable magnetic aerogel as adsorbent for dye. The magnetic aerogels were prepared from sodium carboxymethylcellulose (CMC) hydrogel using citric acid (CA) as the crosslinker, followed by vacuum freeze-drying technique to obtain aerogels. The effects of magnetic Fe3O4 nanoparticle contents on the adsorption properties of the aerogels were investigated. The results show that the as-prepared magnetic composite aerogels exhibit porous structure and display good adsorption and collectable performance for methylene blue (MB) in water with the removal rate of 97.5% in 6 h. The maximum compress strength and absorption capacity of the magnetic aerogel with 1 wt% Fe3O4 nanoparticle loading for MB is 0.13 MPa and 83.6 mg/g, respectively. Aerogels with Fe3O4 nanoparticles exhibited magnetism which enables the aerogels to easily collect. This excellent structure stability and collectability guarantees long-term integrity and floatability of the magnetic aerogels in water.

Keywords: Carboxymethylcellulose sodium; Dye adsorbent; Magnetic aerogel.

MeSH terms

  • Adsorption / drug effects
  • Carboxymethylcellulose Sodium / chemistry*
  • Carboxymethylcellulose Sodium / pharmacology
  • Citric Acid / chemistry*
  • Coloring Agents / isolation & purification
  • Coloring Agents / toxicity
  • Humans
  • Hydrogels / chemistry*
  • Hydrogels / pharmacology
  • Magnetite Nanoparticles / chemistry
  • Metals, Heavy / isolation & purification*
  • Metals, Heavy / toxicity
  • Water / chemistry
  • Water Pollution, Chemical

Substances

  • Coloring Agents
  • Hydrogels
  • Magnetite Nanoparticles
  • Metals, Heavy
  • Water
  • Citric Acid
  • Carboxymethylcellulose Sodium