The anisotropy in the optical constants of quartz crystals for soft X-rays

J Appl Crystallogr. 2021 Feb 19;54(Pt 2):402-408. doi: 10.1107/S1600576720016325. eCollection 2021 Apr 1.

Abstract

The refractive index of a y-cut SiO2 crystal surface is reconstructed from orientation-dependent soft X-ray reflectometry measurements in the energy range from 45 to 620 eV. Owing to the anisotropy of the crystal structure in the (100) and (001) directions, a significant deviation of the measured reflectance at the Si L 2,3 and O K absorption edges is observed. The anisotropy in the optical constants reconstructed from these data is also confirmed by ab initio Bethe-Salpeter equation calculations for the O K edge. This new experimental data set expands the existing literature data for quartz crystal optical constants significantly, particularly in the near-edge regions.

Keywords: anisotropy; optical constants; quartz; soft X-ray reflectometry.

Grants and funding

This work was funded by Horizon 2020 grant 783247 – TAPES3.