Traditional gas sensors are facing the challenge of low power consumption for future application in smart phones and wireless sensor platforms. To solve this problem, self-powered gas sensors are rapidly developed in recent years. However, all reported self-powered gas sensors are suffering from high limit of detection (LOD) toward NO2 gas. In this work, a photovoltaic self-powered NO2 gas sensor based on n-MoS2 /p-GaSe heterojunction is successfully prepared by mechanical exfoliation and all-dry transfer method. Under 405 nm visible light illumination, the fabricated photovoltaic self-powered gas sensors show a significant response toward ppb-level NO2 with short response and recovery time and high selectivity at room temperature (25 °C). It is worth mentioning that the LOD toward NO2 of this device is 20 ppb, which is the lowest of the reported self-powered room-temperature gas sensors so far. The discussed devices can be used as building blocks to fabricate more functional Internet of things devices.
Keywords: 2D materials; all-dry transfer; gas sensing; heterojunction; photovoltaic; self-powered.
© 2021 The Authors. Advanced Science published by Wiley-VCH GmbH.