The measurement of iodine in table salt is vital for the successful implementation of the universal salt iodization (USI) program to fight iodine deficiency disorders (IDDs). This paper presents a smartphone-based optical transduction system for iodine measurement in table salt. The method was based on the response in the blue color space generated by the complex formed between the starch/iodide reagent and iodate in the salt sample. The parameters for the color reaction and for the image capture affected the response and were optimized. A matrix effect caused by NaCl was observed and was eliminated through matrix matching by incorporating NaCl in the standard solutions. The optimized method yielded a highly linear response to iodate concentrations ranging from 10 to 160 mg kg-1 (r = 0.9993) with a limit of detection of 2.8 mg kg-1. The method exhibited good accuracy and precision, based on AOAC standards. It produced results that were in agreement with those obtained using the reference method at the 95% confidence level. The smartphone performs optical transduction, as well as signal processing, to yield a display of the iodate concentration in the salt sample. The use of smartphones presents a simple, inexpensive, portable, and widely available device for on-site analysis of iodate in table salt.
Keywords: Iodate measurement; Optical transduction; Smartphone-based measurement; Table salt iodization.
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