Acridones: Strongly Emissive HIGHrISC Fluorophores

J Phys Chem Lett. 2021 Jun 24;12(24):5703-5709. doi: 10.1021/acs.jpclett.1c01381. Epub 2021 Jun 14.

Abstract

An acridone derivative (N-methyl-difluoro-acridone, NMA-dF) is characterized with respect to its utility as an emitter in organic light emitting diodes (OLEDs). Using steady-state and time-resolved spectroscopy as well as quantum chemistry, its ability to convert singlet and triplet excitons into light was scrutinized. NMA-dF emits in the deep blue range of the visible spectrum. Its fluorescence emission occurs with quantum yields close to 1 and a radiative rate constant of ≈5 × 108 s-1. So, it processes singlet excitons very efficiently. Using 1,4-dichlorobenzene as a sensitizer, it is shown that NMA-dF also converts triplet excitons into light. With the aid of quantum chemistry, this is related to a reverse intersystem crossing starting from a higher triplet state (HIGHrISC).

MeSH terms

  • Acridones / chemistry*
  • Copper / chemistry
  • Fluorescent Dyes / chemistry*

Substances

  • Acridones
  • Fluorescent Dyes
  • Copper