Investigations of Cr(VI) removal by millet bran biochar modified with inorganic compounds: Momentous role of additional lactate

Abstract

In this study, millet bran biochars modified with inorganic compounds (H₃PO₄: P-BC, NaOH: Na-BC and K₂CO₃: K-BC) were prepared and applied for Cr(VI) removal to evaluate the effects of modification on biochars' physicochemical properties. The results showed that Cr(VI) reduction capacity complied with the order of Na-BC > BC > P-BC > K-BC, and reductive groups such as -OH and -NH₂ played considerable roles in electrons donating. Based on this, lactate was added for further investigation of electrons transferring. The results displayed that Cr(VI) removal of all biochars was enhanced tremendously and modified biochars exhibited better Cr(VI) reduction. This may be due to the bridging effect of lactate, which could not only chelate with Cr(VI) via -COOH (or -OH) but also form hydrogen bonds with oxygen or nitrogen containing groups on biochars through the other groups, thus facilitating electrons transferring between biochars and Cr(VI). This work provided an insight into evaluation of the influence of inorganic compounds modification on both electrons donating capability of biochars and electrons transferring potential of biochars combined with lactate in Cr(VI) removal.

Keywords: Cr(VI); Electron donating; Electron transferring; Inorganic compounds; Modified biochar; Sodium lactate.