Theoretical and Experimental Investigations on K-doped SrCo 0.9 Nb 0.1 O 3-δ as a Promising Cathode for Proton-Conducting Solid Oxide Fuel Cells

ChemSusChem. 2021 Sep 20;14(18):3876-3886. doi: 10.1002/cssc.202101100. Epub 2021 Aug 1.


Improving proton conduction in cathodes is regarded as one of the most effective methods to accelerate the sluggish proton-involved oxygen reduction reaction (P-ORR) for proton-conducting solid oxide fuel cells (P-SOFCs). In this work, K+ dopant was used to improve the proton uptake and migration ability of SrCo0.9 Nb0.1 O3-δ (SCN). K+ -doped SCN (KSCN) demonstrated great potential to be a promising cathode for P-SOFCs. Density functional theory calculations suggested that doping with K+ led to more oxygen vacancies and more negative values of hydration enthalpy, which was helpful for the improvement of proton concentration. Importantly, the proton migration barriers could be depressed, benefiting proton conduction. Electrochemical investigations signified that the cell using KSCN cathode had a peak power density of 967 mW cm-2 at 700 °C, about 54.1 % higher than that using a SCN cathode. This research highlights the K+ -doping strategy to improve electrochemical performance of cathodes for P-SOFCs.

Keywords: cathodes; density functional theory calculations; hydration; proton migration; solid oxide fuel cell.