Asymmetrically Functionalized 1,3-Di(2-pyridyl)benzenes: Synthesis and Photophysical Studies

Ekaterina S Starnovskaya; Dmitry S Kopchuk; Yaroslav K Shtaitz; Maria I Savchuk; Igor L Nikonov; Ilya N Egorov; Grigory V Zyryanov; Vladimir L Rusinov; Oleg N Chupakhin

doi:10.1007/s10895-021-02759-4

Asymmetrically Functionalized 1,3-Di(2-pyridyl)benzenes: Synthesis and Photophysical Studies

J Fluoresc. 2022 Jan;32(1):125-133. doi: 10.1007/s10895-021-02759-4. Epub 2021 Oct 7.

Authors

Ekaterina S Starnovskaya^{1

2}, Dmitry S Kopchuk^{1

2}, Yaroslav K Shtaitz¹, Maria I Savchuk^{1

2}, Igor L Nikonov^{3

4}, Ilya N Egorov¹, Grigory V Zyryanov^{1

2}, Vladimir L Rusinov^{1

2}, Oleg N Chupakhin^{1

2}

Affiliations

¹ Ural Federal University, 620002, Yekaterinburg, Russian Federation.
² I. Ya, Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620990, Yekaterinburg, Russian Federation.
³ Ural Federal University, 620002, Yekaterinburg, Russian Federation. igor.nikonov.ekb@gmail.com.
⁴ I. Ya, Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620990, Yekaterinburg, Russian Federation. igor.nikonov.ekb@gmail.com.

PMID: 34618285
DOI: 10.1007/s10895-021-02759-4

Abstract

A convenient synthetic approach to asymmetrically functionalized 1,3-di(2-pyridyl)benzenes starting from 3-(3-bromophenyl)-1,2,4-triazines using sequential aza-Diels-Alder reactions and Stille cross-coupling is reported. Photophysical properties of the obtained compounds are studied.

Keywords: 1,2,4-triazines; 1,3-di(2-pyridyl)benzenes; Aza-Diels–Alder reaction; Cross-coupling; Fluorescence.