Cationic coordination polymers with thirteen-fold interpenetrating dia networks: selective coloration and ion-controlled photochromism

Xin Li; Yanger Li; Xiaoman Yang; Chaoyue Yan; Kai Zhang; Xiaoxiao Liang; Jinli Zhang; Yanli Gai; Kecai Xiong

doi:10.1039/d1cc05255a

Cationic coordination polymers with thirteen-fold interpenetrating dia networks: selective coloration and ion-controlled photochromism

Chem Commun (Camb). 2021 Nov 23;57(93):12496-12499. doi: 10.1039/d1cc05255a.

Authors

Xin Li¹, Yanger Li¹, Xiaoman Yang¹, Chaoyue Yan¹, Kai Zhang¹, Xiaoxiao Liang¹, Jinli Zhang¹, Yanli Gai¹, Kecai Xiong^{1

2}

Affiliations

¹ School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, P. R. China. kcxiong@jsnu.edu.cn.
² State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.

PMID: 34750599
DOI: 10.1039/d1cc05255a

Abstract

A novel Cd-based cationic coordination polymer (Cd-CCP) constructed using viologen derivatives, which exhibits an unusual thirteen-fold interpenetrating diamondoid network, has been synthesized. Notably, Cd-CCP displays selective and naked-eye distinguished coloration and ion-controlled photochromism towards halide anions.