Reaction Mechanism of ZrB2-ZrC Formation in Ni-Zr-B4C System Analyzed by Differential Scanning Calorimetry

Jiaying Xu; Pengfei Ma; Binglin Zou

doi:10.3390/ma14216467

Reaction Mechanism of ZrB₂-ZrC Formation in Ni-Zr-B₄C System Analyzed by Differential Scanning Calorimetry

Materials (Basel). 2021 Oct 28;14(21):6467. doi: 10.3390/ma14216467.

Authors

Jiaying Xu¹, Pengfei Ma¹, Binglin Zou²

Affiliations

¹ Jilin Institute of Chemical Technology, College of Science, Jilin 132022, China.
² State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

Abstract

The reaction mechanism of ZrB₂-ZrC formation in a 30% Ni-Zr-B₄C system under argon was revealed by using differential scanning calorimetry (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the reaction mechanism in the Ni-Zr-B₄C system was complex. Initially, Ni_xZr_y and Ni_xB_y intermetallics were formed via solid-state diffusion reactions between Ni, B₄C and Zr. Then, the eutectic reaction between Ni₂B and Ni₄B₃ lead to the formation of Ni-B liquid. The free C atoms dissolved into the Ni-B liquid to form a Ni-B-C ternary liquid, and then part of the Zr powder dissolved into the surrounding Ni-B-C ternary liquid to form Ni-Zr-B-C quaternary liquid. Finally, ZrB₂ and ZrC formed and precipitated out of the saturated liquid. The eutectic liquid plays an important role during the formation of ZrB₂-ZrC.

Keywords: ZrB2-ZrC; combustion synthesis; differential scanning calorimetry; reaction mechanism; self-propagation high-temperature synthesis.

Abstract

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