Review on metal dissolution characteristics and harmful metals recovery from electronic wastes by supercritical water

Abstract

Supercritical water (SCW) technology can be applied as an efficient and environment-friendly method to recover toxic or complex chemical wastes. Separation and chemical reactions under supercritical conditions may be realized by changing the temperature, pressure, and other operating parameters to adjust the physical and chemical properties of water. However, salt deposition and corrosion are often encountered during the treatment of inorganic substances, which will hinder the commercial applications of SCW technology. The solubility of salt in high pressure/temperature water forms the theoretical basis for studying the recovery of metal salts in supercritical water and understanding salt deposition. Therefore, this work systematically and objectively reviews different research methods used to analyze salt solubility in high pressure/temperature water, including the experimental method, prediction theoretical modeling, and computer simulation method; the research status and existing data of this parameter are also analyzed. The purpose of this review is to provide ideas and references for follow-up research by providing a comprehensive overview of salt solubility research methods and the current situation. Suggestions for more efficient metal recovery through technology integration are also provided.

Keywords: Inorganic metal compounds; Metal recovery; Organic metal compounds; Salt solubility; Supercritical water.