A study of negative-thermal-quenching (Ba/Ca)AlSi5O2N7:Eu2+ phosphors

Hongping Ma; Shixu Tao; Youjie Hua; Jun Zheng; Luyi Lou; Yiheng Ping; Peng Qiao

doi:10.1039/d1dt02752b

A study of negative-thermal-quenching (Ba/Ca)AlSi₅O₂N₇:Eu²⁺ phosphors

Dalton Trans. 2021 Dec 7;50(47):17792-17799. doi: 10.1039/d1dt02752b.

Authors

Hongping Ma¹, Shixu Tao¹, Youjie Hua², Jun Zheng¹, Luyi Lou¹, Yiheng Ping¹, Peng Qiao³

Affiliations

¹ School of Mechanical and Energy Engineering, Zhejiang University of Science and Technology, Hangzhou 310023, China. hongpingma2019@163.com.
² College of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, China.
³ Zhejiang Academy of Special Equipment Science, Hangzhou 314415, China.

PMID: 34821887
DOI: 10.1039/d1dt02752b

Abstract

Phosphor is an important part of the new generation of light-emitting diodes (LEDs), which requires high luminous intensity and high-temperature resistance. In this study, a series of excellent (Ba_1-x-yCa_x)AlSi₅O₂N₇:yEu²⁺ phosphors was developed, which were synthesized by a high-temperature solid-state reaction in a reducing atmosphere. In addition, the crystallinity and luminescence intensity of the samples could be enhanced by some amount of Ca²⁺ substitution. The luminescence intensity was the highest when the Eu²⁺ concentration reached 0.06. Furthermore, the thermal stability of the luminescence was studied in detail. The results were satisfactory, showing that the luminescence intensity of the (Ba_1-xCa_x)AlSi₅O₂N₇:Eu²⁺ phosphors exhibited unique negative-thermal-quenching characteristics both at high (273-473 K) and low (4-273 K) temperatures. And the phosphor combined with UV LED chip and red phosphor Sr₂Si₅N₈:Eu²⁺ can achieve a CRI of 90.4 in white LED application which indicated the (Ba_1-xCa_x)AlSi₅O₂N₇:Eu²⁺ phosphor has potential in LED applications.