Stretch-Enhanced Anisotropic Wetting on Transparent Elastomer Film for Controlled Liquid Transport

ACS Nano. 2021 Dec 28;15(12):19981-19989. doi: 10.1021/acsnano.1c07512. Epub 2021 Nov 29.

Abstract

Direction-controlled wetting surfaces, special for lubricating oil infused anisotropic surfaces, have attracted great research interest in directional liquid collection, expelling, transfer, and separation. Nonetheless, there are still existing difficulties in achieving directional and continuous liquid transport. Herein, we present a strategy to achieve directional liquid transport on transparent lubricating oil infused elastomer film with V-shaped prisms microarray (VPM). The results reveal that the water wetting direction in the parallel and staggered arrangement of the VPM structure surface with lubricating oil infusion is the opposite, which is completely different from the wetting direction on the usual VPM surface in air. Moreover, asymmetric stretching can enhance or weaken the directional water wetting tendency on the lubricating oil infused VPM elastomer film and even can reverse the droplet wetting direction. In a closed moist environment, tiny droplets gradually coalesce and then slip away from the lubricating oil infused VPM surface to keep the surface transparent, due to the cooperation of imbalanced Laplace pressure, resulting from the anisotropic geometric structures, varying VPMs spacing, and gravity. Thus, this work provides a paradigm to design and fabricate a type of surface engineering material in the application fields of directional expelling, liquid collection, anti-biofouling, anti-icing, drag reduction, anticorrosion, etc.

Keywords: anisotropic wetting; liquid transport; lubricating oil infused surface; micro/nanostructure; stretch enhanced.