Rausuquinone, a non-glycosylated pluramycin-class antibiotic from Rhodococcus

J Antibiot (Tokyo). 2022 Feb;75(2):86-91. doi: 10.1038/s41429-021-00489-0. Epub 2021 Nov 30.

Abstract

A new pluramycin-class polyketide, rausuquinone (1), and its known congener hydramycin (2) were isolated from the culture extract of the deep-sea water-derived Rhodococcus sp. RD015140. Compound 1 possesses a γ-pyrone-fused anthraquinone core with a 3-butene-1,2-diol side chain. Structures of 1 was determined by extensive analysis of 1D and 2D NMR spectroscopic data. Compound 1 showed antimicrobial activity against Gram-positive bacteria. This is the first discovery of aromatic polyketides from the genus Rhodococcus.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aminoglycosides / chemistry
  • Aminoglycosides / pharmacology*
  • Anthraquinones / chemistry
  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / pharmacology*
  • Antioxidants / chemistry
  • Antioxidants / pharmacology
  • Fermentation
  • Gram-Positive Bacteria / drug effects
  • Magnetic Resonance Spectroscopy
  • Microbial Sensitivity Tests
  • Rhodococcus / chemistry
  • Rhodococcus / metabolism*
  • Seawater / microbiology

Substances

  • Aminoglycosides
  • Anthraquinones
  • Anti-Bacterial Agents
  • Antioxidants
  • pluramycin