Superior removal of dyes by mesoporous MgO/g-C3N4 fabricated through ultrasound method: Adsorption mechanism and process modeling

A Modwi; L Khezami; M G Ghoniem; P Nguyen-Tri; O Baaloudj; A Guesmi; F K AlGethami; M S Amer; A A Assadi

doi:10.1016/j.envres.2021.112543

Superior removal of dyes by mesoporous MgO/g-C₃N₄ fabricated through ultrasound method: Adsorption mechanism and process modeling

Environ Res. 2022 Apr 1:205:112543. doi: 10.1016/j.envres.2021.112543. Epub 2021 Dec 13.

Authors

A Modwi¹, L Khezami², M G Ghoniem², P Nguyen-Tri³, O Baaloudj⁴, A Guesmi², F K AlGethami², M S Amer⁵, A A Assadi⁶

Affiliations

¹ Department of Chemistry, College of Science and Arts, Qassim University, Ar Rass, Saudi Arabia.
² Imam Mohammad Ibn Saud Islamic University (IMSIU), College of Science, Chemistry Department, Riyadh, Saudi Arabia.
³ Laboratory of Advanced Materials for Energy and Environment, University Du Quebec Trois-Rivieres (UQTR), 3351, C.P. 500, Trois-Rivieres, Quebec, G9A 5H7, Canada. Electronic address: phuong.nguyen-tri@uqtr.ca.
⁴ Laboratory of Reaction Engineering, Faculty of Mechanical Engineering and Process Engineering USTHB, BP 32, Algiers, Algeria.
⁵ Electrochemical Sciences Research Chair (ESRC), Chemistry Department, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.
⁶ Univ Rennes, ENSCR / UMR CNRS 6226, 11 Allée de Beaulieu, 35700, Rennes, France.

PMID: 34915029
DOI: 10.1016/j.envres.2021.112543

Abstract

The present research concerns the synthesis of a mesoporous composite characterized with high surface area and superior adsorption capacity in order to investigate its efficacity in removing hazardous and harmful dyes molecules from water. The synthesized mesoporous composite, MgO/g-C₃N₄ (MGCN), was successfully prepared through the sonication method in a methanolic solution followed by an evaporation and a calcination process. The configuration, crystalline phase, surface properties, chemical bonding, and morphological study of the fabricated nanomaterials were investigated via XRD, BET, FESEM, HRTEM, XPS, and FTIR instrumentation. The obtained nanomaterials were used as sorbents of Congo Red (CR) and Basic Fuchsin (BF) dyes from aqueous solutions. Batch elimination experimental studies reveal that the elimination of CR and BF dyes from an aqueous solution onto the MGCN surface was pH-dependent. The highest removal of CR and BF pollutants occurs, respectively, at pH 5 and 7. The absorptive elimination of CR and BF dyes into the MGCN surface was well-fitted with a pseudo-second-order kinetics and Langmuir model. In this concern, the maximum nanocomposite elimination capacity for CR and BF was observed to be 1250 and 1791 mg g^-1, respectively. This investigation confirms that MGCN composite is an obvious and efficient adsorbent of CR, BF, and other organic dyes from wastewater.

Keywords: BF and CR dyes removal; Kinetics investigation; MGCN sorbent; pH impact.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Adsorption
Coloring Agents* / chemistry
Hydrogen-Ion Concentration
Kinetics
Magnesium Oxide
Water Pollutants, Chemical* / analysis

Substances

Coloring Agents
Water Pollutants, Chemical
Magnesium Oxide