Flexible hydrogels with integration of excellent mechanical and electrical properties are well suited for applications as wearable electronic sensors, and others. Self-adhesion is an important feature of wearable sensors. However, the usual isotropic- adhesion hydrogels have the drawback of poor anti-interference, which negatively affects their applications. In this study, we developed asymmetric-adhesion and tough lignin reinforced hydrogels in a facile two-step process: 1) PAA hydrogels, with lignin as the binder and conductive filler, were first prepared; 2) the asymmetric-adhesion property was imparted to lignin reinforced hydrogel by simple soaking of the top portion of the hydrogel in CaCl2 solution. The as-obtained asymmetric-adhesion lignin reinforced hydrogel was assembled into a wearable sensor, which shows excellent anti-interference and accurate and stable collections of sensing signals, with its gauge factor (GF) of 2.51 (in the strain range of 0-51.5%). In addition, the tough hydrogel is capable of generating electricity upon moist air sweeping through it, showing excellent energy conversion capabilities, with open-circuit voltage of as high as 306.6 mV. These results provided new prospects for the application of polyelectrolyte hydrogel materials in the fields of wet-to-electric conversion and wearable electronic sensors.
Keywords: Anti-interference; Asymmetric adhesion; Lignin reinforced hydrogels; Moist air induced electricity generator.
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