Triazine herbicides (TRZHs) are widely used in agricultural production, but their improper use can threaten the environment and organisms. Herein, rapid extraction of four chlorotriazine herbicides (Cl-TRZHs) in irrigation water was achieved using an ionic liquid modified porous m-aminophenol formaldehyde resin (IL-MAPFR) as a dispersive filter extraction (DFE) adsorbent. The IL-MAPFR shows excellent adsorption performance for four Cl-TRZHs (simazine, cyanazine, atrazine, and terbuthylazine), with a large specific surface area (158.1 m2 g-1) and fast mass transfer (2 min). The adsorption process conforms to the pseudo-second-order kinetics and Freundlich isotherm models. The four Cl-TRZHs were concentrated 12-16-fold after the IL-MAPFR-DFE method. Coupled with high-performance liquid chromatography, an accurate and sensitive determination method for four Cl-TRZHs in irrigation water was established, with low detection limit (0.11-0.20 ng mL-1), high recoveries (91.5-110%), and excellent precision (relative standard deviations (RSDs) ≤ 8.4%). This method provides technical support for agricultural irrigation water quality monitoring and has great application potential in water safety, especially pesticide residues.
Keywords: chlorotriazine herbicides; dispersive filter extraction; ionic liquid; irrigation water; porous polymer.